title: Surface enhanced Raman scattering of new acridine based fluorophore adsorbed on silver electrode

dc.contributor.author

value: Solovyeva, Elena V.

value: Myund, Liubov A.

value: Denisova, Anna S.

dc.description.abstract

value: 4,5-bis(N,N-di(2-hydroxyethyl)iminomethyl)acridine (BHIA) is a new acridine based fluoroionophore and a highly-selective sensor for cadmium ion. The direct interaction of the aromatic nitrogen atom with a surface is impossible since there are bulky substituents in the 4,5- positions of the acridine fragment. Nevertheless BHIA molecule shows a reliable SERS spectrum while adsorbed on a silver electrode. The analysis of SERS spectra pH dependence reveals that BHIA species adsorbed on a surface can exist in both nonprotonated and protonated forms. The adsorption of BHIA from alkaline solution is accompanied by carbonaceous species formation at the surface. The intensity of such “carbon bands” turned out to be related with the supporting electrolyte (KCl) concentration. Upon lowering the electrode potential the SERS spectra of BHIA do not undergo changes but the intensity of bands decreases. This indicates that the adsorption mechanism on the silver surface is realized via aromatic system of acridine fragment. In case of such an adsorption mechanism the chelate fragment of the BHIA molecule is capable of interaction with the solution components. Addition of Cd2+ ions to a system containing BHIA adsorbed on a silver electrode in equilibrium with the solution leads to the formation of BHIA/Cd2+ complex which desorption causes the loss of SERS signal.

dc.relation.ispartofseries

value: Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy;149

dc.subject

value: Surface-enhanced Raman spectroscopy

value: fluorophore

value: acridine derivatives

value: adsorption


title: Transit network design for green vehicles routing

dc.contributor.author

value: Zakharov, Victor V.

value: Krylatov, Alexander Y.

dc.identifier.citation

value: SCOPUS

dc.description.abstract

value: Transport of modern worldwide cities generates harmful emissions that accounts for nearly half of the total pollution in urban areas. Therefore local governments are forced to stimulate appearance of new fuels and technological innovations in urban mobility. Nevertheless there is a lack of methodological tools for supporting decision makers in spheres of motivation for using green vehicles by drivers and allocation available green capacity. This paper is devoted to the problem of green and non-green traffic flow assignment on the network consisting of green and non-green routes. The approach of defining green routes (green subnetwork) which are fully loaded and provide less travel time for green vehicles are developed. Conditions of well-balanced green subnetwork are obtained explicitly for the network of parallel routes.

dc.language.iso

value: en

dc.publisher

value: Springer International Publishing

dc.subject

value: routing

value: Wardrop equilibrium

value: green routes allocation

value: transit network design

dc.type

value: Article

filename: 1 page.pdf

format: Adobe PDF


title: Corrigendum to "Solubility, liquid-liquid equilibrium and critical states for the quaternary system acetic acid-ethanol-ethyl acetate-water at 303.15K and 313.15K" [Fluid Phase Equilib. 373 (2014) 72-79]

dc.contributor.author

value: Toikka, M.

value: Samarov, A.

value: Trofimova, M.

value: Golikova, A.

value: Tsvetov, N.

value: Toikka, A.

dc.description.abstract

value: Corrigendum to “Solubility, liquid–liquid equilibrium and critical states for the quaternary system acetic acid–ethanol–ethyl acetate–water at 303.15 K and 313.15 K” [Fluid Phase Equilib. 373 (2014) 72–79]

dc.publisher

value: Elsevier

dc.title

filename: Corrigendum to “Solubility, liquid–liquid equilibrium and critical states for the quaternary system acetic acid–ethanol–ethyl acetate–water at 303.15 K and 313.15 K”.pdf


title: Competitive Green-Vehicle Assignment on a Transportation Network

dc.contributor.author

value: Zakharov, Victor V.

value: Krylatov, Alexander Y.

dc.description.abstract

value: Currently, there is a lack of methodological tools available to support decision makers with regard to encouraging the use of green vehicles and in the allocation of available green capacity. This chapter is devoted to the problem of green and non-green traffic flow assignment on a network consisting of green and non-green routes. The analysis of a competitive framework is performed, and an approach for defining green routes (i.e., green subnetworks) that are fully loaded and provide less travel time for green vehicles is developed using Wardrop and Nash traffic flow assignments. The conditions of a balanced green subnetwork are also defined explicitly for a network of parallel routes.

dc.publisher

value: Nova Science Publishers, Inc.

dc.type

value: Book chapter


title: Diffusion slowdown in the nanostructured liquid Ga-Sn alloy

dc.contributor.author

value: Podorozhkin, DY

value: Charnaya, EV

value: Lee, MK

value: Chang, LJ

value: Haase, J

value: Michel, D

value: Kumzerov, Ya

value: Fokin, AV

dc.description.abstract

value: The diffusion of gallium in liquid Ga-Sn alloy embedded into different porous silica matrices was studied by NMR. Spin relaxation was measured for two gallium isotopes, Ga-71 and Ga-69, at two magnetic fields. Pronounced rise of quadrupole contribution to relaxation was observed for the nanostructured alloy which increased with decreasing the pore size. The correlation time of atomic mobility was evaluated and found to be much larger than in the relevant bulk melt which evidenced a pronounced diffusion slowdown in the Ga-Sn alloy under nanoconfinement. It is shown that the diffusion was slower by a factor of 30 for the alloy within 7 nm pores. The spectral densities of electric field gradients at zero frequency were found to double for the finest pores. The Knight shift was found to decrease but slightly for the nanostructured alloy.

dc.language.iso

value: en

dc.title

format: JPEG


title: Modification of hydrophobic sorbents by cobalt chloride in order to concentrate low molecular polar organic substances from the air for subsequent gas chromatographic determination.

dc.contributor.author

value: Rodinkov, O.V.

value: Zhuravleva, G.A.

value: Bugaichenko, A.S.

value: Viktorova, M.I.

value: Postnov, V.N.

value: Novikov, A.G.

dc.description

value: Studies were carried out using the equipment centers SPSU: Centre for innovative Technologies of Composite Nanomaterials and Chemistry Education Centre.

dc.description.abstract

value: The article presents a new method of modification of hydrophobic sorbents. To improve sorption pre-concentration of polar organic compounds in the air analysis, these sorbents are coated with cobalt chloride. This modification increases retention volume of lower alcohols by 5-10 fold as compared to that of unmodified sorbents and solves the problem of gas-chromatographic determination at 1-2 ppb (micrograms / m3) by using the most common flame ionization detector. It should be noted that the modification of hydrophobic sorbents by cobalt chloride has little influence on their porosimetry parameters (specific surface area, proportions of meso- and micropores) and modified sorbents are capable of retaining hydrophobic nonpolar and weakly polar analytes as well as original unmodified sorbents. Thus, a fairly simple procedure leads to a large positive effect.

dc.description.sponsorship

value: The authors thank Russian Foundation for Basic Research (project 15-03-05082a.

dc.subject

value: Cobalt chloride

value: Pre-concentration

value: Air analysis

value: Sorbents

value: Volatile organic compounds

dc.type

value: Article


title: Shock-induced structures in copper

dc.contributor.author

value: Meshcheryakov, Yuri

value: Zhigacheva, Natalya

value: Vyvenko, Oleg

value: Bondarenko, Anton

dc.description.abstract

value:
Shock loading of M3 copper within strain rate range of 5·106
-5,7·106 s
-1 reveals a
nucleation of structural objects of 5-30 µm in diameter, which present the three dimensional
frameworks composed from shear bands of 50-200 nm spacing. The structures are shown to
be nucleated by means of interference of longitudinal and periphery release waves. Transition
of the material into structure unstable state responsible for the shear banding happens when
rate of change of the velocity variance at the mesoscale becomes higher than the rate of
change of the mean particle velocity. The sites of nucleation of 3D-structures are speculated
to be the staking faults generated under action of chaotic velocity pulsations relevant to
dynamic deformation. The physical model for formation of 3D-structures takes into account
the intersection of the partial dislocations and Lomer - Cottrell barriers.

dc.publisher

value: Institute of Problems of Mechanical Engineering

dc.subject

value: Copper

value: Microstructure

dc.title

value: Shock-induced structures in copper


title: Signal control in a congested traffic area

dc.contributor.author

value: Krylatov, Alexander Y.

value: Zakharov, Victor V.

value: Malygin, Igor G.

dc.identifier.citation

value: SCOPUS

dc.description.abstract

value: The most travel delays in daily trips in modern large urban areas take place primarily at signal-controlled junctions due to regular interruption by alternating traffic lights. Therefore in urban traffic control road networks alleviation increasing of traffic congestion at signalized junctions becomes one of the most significant issues, facing decision makers at various levels of management. This paper is devoted to development of methodological tools to cope with problem of settings traffic signals for congested transportation network. The global traffic control system is assumed to define timing parameters of signals for the whole transportation network. Users of network are believed to react on any fixed signal setting, assigning according to user-equilibrium of Wardrop. Thus, the global optimal signal settings problem under user network equilibrium conditions is formulated as bi-level optimization program. When travel time is modeled by modified linear BPR cost function, the user-equilibrium flow patterns for two intersecting networks of parallel routes could be obtained as explicit condition of the lower programming level.

dc.language.iso

value: en

dc.publisher

value: IEEE


title: Nuclear magnetic resonance study of a Bi2Te3 topological insulator

dc.contributor.author

value: Podorozhkin, DY

value: Charnaya, EV

value: Antonenko, A

value: Mukhamad'yarov, R

value: Marchenkov, VV

value: Naumov, SV

value: Huang, JCA

value: Weber, HW

value: Bugaev, AS

dc.description.abstract

value: he results of the nuclear magnetic resonance (NMR) study of a grown high-quality Bi2Te3 semiconductor single crystal have been presented. Signals from the Te-125 isotope were detected by the spin echo method in the range from 10 K to room temperature. It was found that the NMR spectrum consists of two lines. The line with a positive shift of the resonance frequency corresponded to the bulk of the sample. The line with a negative shift was interpreted as a signal from the surface of the single crystal. The temperature and orientational dependences of the positions of the NMR line of nuclei in the bulk of the crystal were studied. It was shown that the shifts are mainly determined by the Knight shift due to the interaction with mobile charge carriers. The thermoactivation character of the concentration of mobile charges in the crystal under study, which corresponds to the intrinsic conductance, was proved, and the energy parameters of the thermoactivation processes were calculated.

dc.type

value: Article


dc.contributor.author

value: Zakharov, Victor V.

dc.description.abstract

value: Currently, there is a lack of methodological tools available to support decision makers with regard to encouraging the use of green vehicles and in the allocation of available green capacity. This chapter is devoted to the problem of green and non-green traffic flow assignment on a network consisting of green and non-green routes. The analysis of a competitive framework is performed, and an approach for defining green routes (i.e., green subnetworks) that are fully loaded and provide less travel time for green vehicles is developed using Wardrop and Nash traffic flow assignments. The conditions of a balanced green subnetwork are also defined explicitly for a network of parallel routes.

dc.publisher

value: Nova Science Publishers, Inc.

dc.title

value: Competitive Green-Vehicle Assignment on a Transportation Network

value: Book chapter


title: Easily Vaporizable Ionic Liquids – No Contradiction!

dc.contributor.author

value: Köckerling Martin, Peppel Tim

value: Thiele Philipp, Verevkin Sergey P.

value: Emel’yanenko Vladimir N., Samarov Artemiy A.

value: Ruth Wolfgang

dc.description.abstract

value:
It was a big surprise to see crystals of an ionic liquid (IL) forming by sublimation at room temperature. ILs are gen- erally accepted to have negligible vapour pressures at ele- vated temperatures, making their sublimation or distillation very difficult. ILs that sublime easily contain silylimid- azolium-based cations. In order to establish the details of the unusual behaviour of this subclass of ILs, a combined spec- troscopic, X-ray crystallographic, physicochemical and theo-
retical characterization was performed. The results are com- pared with those of other easily vaporizable compounds, like ammonium chloride and naphthalene. The single-crystal X- ray structure analysis of one of these compounds, N-methyl- N?-dimethyl(phenyl)silylimidazolium chloride (monoclinic, C2/c), clearly shows the existence of isolated ions, demon- strating that the compound is an ionic liquid.

dc.language.iso

value: en

dc.relation.ispartofseries

value: European Journal of Inorganic Chemistry;24

dc.subject

value: Ionic liquids

value: Silylimidazoles

value: Boiling point

value: Solid-state structures

value: Thermochemistry

value: Sublimation

filename: Köckerling et al. - 2015 - Easily Vaporizable Ionic Liquids - No Contradiction!.pdf


title: Two-Component Catalytic Systems Based on Platinum(II) and Platinum(0) Complexes for Hydrosilylation of Polysiloxanes

dc.contributor.author

value: Islamova, R.M.

value: Vlasov, A.V.

value: Dobrynin, M.V.

value: Masloborodova, E.A.

value: Kaganova, E.V.

dc.description.abstract

value:
The effect of the binary catalytic systems [the Karstedt catalyst–platinum(II) isocyanide complex]
of the cure of vinyl-containing polydimethylsiloxane and hydride-containing siloxane oligomer via the
hydrosilylation reaction has been studied.

dc.description.sponsorship

value: This work was performed in the frame of the Federal Target Program (agreement no. 14.576.21.0028, synthesis of the polymers 4 and 5) and was financially supported by the Russian Scientific Foundation (grant no. 14-43-00017, preparation of the complexes 2 and 3 and study of the catalytic activity).

value: hydrosilylation, curing, polysiloxane, the Karstedt catalyst, platinum(II) isocyanide complex, catalytic system

dc.type

value: Article

filename: Islamova_Rus. J. of Gen. Chem._2015.pdf


title: Acid-Promoted Reaction of Trifluoromethylated Allyl Alcohols with Arenes. Stereoselective Synthesis of CF3‑Alkenes and CF3‑Indanes

dc.contributor.author

value: Kazakova, Anna N.

value: Iakovenko, Roman O.

value: Boyarskaya, Irina A.

value: Nenajdenko, Valentine G.

value: Vasilyev, Aleksander V.

dc.description.abstract

value:
Reaction of 4-aryl-1,1,1-trifluorobut-3-en-2-ols with arenes under activation with anhydrous FeCl3 or FSO3H was studied. We found that the transformation led to trifluoromethylated alkenes or 1-trifluoromethylated
indanes (CF3-indanes). The formation of these two types of reaction products strongly depends on the nucleophilicity of the starting arene and the electrophilicity of cationic intermediates generated from CF3-allyl alcohols under reaction conditions. Benzene, anisole, veratrole, and ortho-xylene lead exclusively to CF3-alkenes with an E-configuration. More π-donating polymethylated arenes (pseudocumene, mesitylene) afford only CF3-indanes with a predominantly cis-orientation of substituents at positions 1 and 3 of the indane ring. Meta- and para-xylenes show an intermediate behavior; they may form both CF3-alkenes
and/or CF3-indanes. The mechanisms of the investigated transformations are discussed.

dc.description.sponsorship

value: This work was supported by Saint Petersburg State University (grant nos. 12.50.1558.2013 and 12.38.195.2014)

dc.language.iso

value: en

dc.publisher

value: ACS Publications

dc.relation.ispartofseries

value: Journal of Organic Chemistry;80

dc.subject

value: Trifluoromethylated Allyl Alcohols

value: arenes

value: Brønsted or Lewis acids


title: Reactions of CF3-enones with arenes under superelectrophilic activation: a pathway to trans-1,3-diaryl-1-CF3-indanes, new cannabinoid receptor ligands

dc.contributor.author

value: Muzalevskiy, Vasiliy M.

value: Ivanov, Alexander Yu.

value: Chicca, Andrea

value: Petrucci, Vanessa

value: Gertsch, Jürg

value: Krasavin, Mikhail

value: Starova, Galina L.

value: Zolotarev, Andrey A.

value: Avdontceva, Margarita S.

dc.description.abstract

value:
4-Aryl-1,1,1-trifluorobut-3-en-2-ones ArCHvCHCOCF3 (CF3-enones) react with arenes in excess of  Brønsted superacids (TfOH, FSO3H) to give, stereoselectively, trans-1,3-diaryl-1-trifluoromethyl indanes in
35–85% yields. The reaction intermediates, the O-protonated ArCHvCHC(OH+)CF3 and the O,C-diprotonated ArHC+CH2C(OH+)CF3 species, have been studied by means of 1H, 13C, 19F NMR, and DFT calculations. Both types of the cations may participate in the reaction, depending on their electrophilicity and
electron-donating properties of the arenes. The formation of CF3-indanes is a result of cascade reaction
of protonated CF3-enones to form chemo-, regio- and stereoselectively three new C–C bonds. The
obtained trans-1,3-diaryl-1-trifluoromethyl indanes were investigated as potential ligands for cannabinoid
receptors CB1 and CB2 types. The most potent compound showed sub-micromolar affinity for both
receptor subtypes with a 6-fold selectivity toward the CB2 receptor with no appreciable cytotoxicity
toward SHSY5Y cells.

dc.description.sponsorship

value: This work was supported by Saint Petersburg State University (grant no. 12.50.1558.2013, and 12.38.195.2014).

dc.publisher

value: The Royal Society of Chemistry

dc.subject

value: Brønsted superacids

value: superelectrophilic activation

dc.title

filename: Org Bio Mol, 2015.pdf


title: Generalized exhausters: Existence, construction, optimality conditions

dc.contributor.author

value: Abbasov, Majid Elkhan ogli

dc.description.abstract

value: In this work a generalization of the notion of exhauster is considered. Exhausters are new tools in nonsmooth analysis introduced in works of Demyanov V.F., Rubinov A.M., Pshenichny B.N. In essence, exhausters are families of convex compact sets, allowing to represent the increments of a function at a considered point in an infmax or supmin form, the upper exhausters used for the first representation, and the lower one for the second representation. Using this objects one can get new optimality conditions, find descent and ascent directions and thus construct new optimization algorithms. Rubinov A.M. showed that an arbitrary upper or lower semicontinuous positively homogenous function bounded on the unit ball has an upper or lower exhausters respectively. One of the aims of the work is to obtain the similar result under weaker conditions on the function under study, but for this it is necessary to use generalized exhausters - a family of convex (but not compact!) sets, allowing to represent the increments of the function at a considered point in the form of infsup or supinf. The resulting existence theorem is constructive and gives a theoretical possibility of constructing these families. Also in terms of these objects optimality conditions that generalize the conditions obtained by Demyanov V.F., Abbasov M.E. are stated and proved. As an illustration of obtained results, an example of n-dimensional function, that has a non-strict minimum at the origin, is demonstrated. A generalized upper and lower exhausters for this function at the origin are constructed, the necessary optimality conditions are obtained and discussed.

dc.language.iso

value: en

dc.publisher

value: Journal of Industrial and Management Optimization (JIMO)

dc.type

value: Article

description: GENERALIZED EXHAUSTERS: EXISTENCE, CONSTRUCTION, OPTIMALITY CONDITIONS


title: Second-Order Minimization Method for Nonsmooth Functions Allowing Convex Quadratic Approximations of the Augment

dc.description.abstract

value: Second-order methods play an important role in the theory of optimization. Due to the usage of more information about considered function, they give an opportunity to find the stationary point faster than first-order methods. Well-known and sufficiently studied Newton’s method is widely used to optimize smooth functions. The aim of this work is to obtain a second-order method for unconstrained minimization of nonsmooth functions allowing convex quadratic approximation of the augment. This method is based on the notion of coexhausters—new objects in nonsmooth analysis, introduced by V. F. Demyanov. First, we describe and prove the second-order necessary condition for a minimum. Then, we build an algorithm based on that condition and prove its convergence. At the end of the paper, a numerical example illustrating implementation of the algorithm is given.

dc.publisher

value: Journal of Optimization Theory and Applications

value: Springer US


dc.contributor.author

value: Peshkova, M.A.

value: Koltashova, E.S.

value: Khripoun, G.A.

value: Mikhelson, K.N.

dc.identifier.citation

value: 3.	M.A. Peshkova, E.S. Koltashova, G.A. Khripoun, K.N. Mikhelson, Improvement of the upper limit of the ISE Nernstian response by tuned galvanostatic polarization, Electrochimica Acta 167 (2015) 187-193

dc.description.abstract

value:
Galvanostatic polarization with a tuned anodic current density is successfully applied for the
improvement of the upper detection limit (UDL) of a Cd2+-selective electrode with PVC membrane
containing neutral ionophore N,N,N0,N0-tetradodecyl-3,6-dioxaoctanedithioamide (ETH 5435). The UDL
of the anodically polarized electrode is 1.0 M CdCl2 whereas the traditional zero-current UDL is 0.05 M.
The polarization regularities obey the Ohm’s law, and this makes the basis for the algorithm of the
optimization of the polarizing current density for a given Cd2+ concentration and for the analytical
application of the electrode.

dc.publisher

value: Elsevier Science Publishers

dc.subject

value: Ion-selective electrodes

value: galvanostatic polarization

value: coextraction

dc.title

format: Microsoft Word XML


title: Synthesis of Razumikhin and Lyapunov-Krasovskii approaches to stability analysis of time-delay systems

dc.contributor.author

value: Medvedeva, Irina V.

value: Zhabko, Alexey P.

dc.description.abstract

value: In this paper, a necessary and sufficient condition for the exponential stability of linear systems with several time-delays is presented. Such a condition is based on the construction of quadratic lower bounds for the Lyapunov-Krasovskii functionals on the special Razumikhin-type set of functions. The result reveals a constructive procedure for the stability analysis whose application is illustrated with examples.

dc.publisher

value: Elsevier Ltd

dc.subject

value: Lyapunov-Krasovskii functionals

value: Time-delay system

value: Stability

value: Stability domains

filename: 2015 Automatica final.pdf


title: Stable cooperation in linear-quadratic differential games with nontransferable payoffs

dc.contributor.author

value: Tur, Anna

dc.identifier.citation

value: "Stability and Control Processes" in Memory of V.I. Zubov (SCP), 2015 International Conference

dc.description.abstract

value: The problem of strategically supported cooperation in linear-quadratic differential games is considered. It is assumed, that the cooperative agreement is reached and each player gets his payoff according to the payoff distribution procedure [5]. Following [3], to punish those who violate this agreement, the special game, which differs from initial only by payoffs of players on cooperative trajectory is constructed. It is shown that in the new game there exists an ε-equilibrium with payoffs of players equal to corresponding payoffs of players in cooperative solution of initial game.

dc.description.sponsorship

value: This research was supported by the research grant 9.38.245.2014 at St. Petersburg State University.

dc.language.iso

value: en

dc.publisher

value: IEEE

dc.type

value: Preprint


title: Determination of urine ionic composition with potentiometric multisensor system

dc.contributor.author

value: Yaroshenko, Irina

value: Kirsanov, Dmitry

value: Kartsova, Lyudmila

value: Sidorova, Alla

value: Borisova, Irina

value: Legin, Andrey

dc.description.abstract

value: The ionic composition of urine is a good indicator of patient's general condition and allows for diagnostics of certain medical problems such as e.g., urolithiasis. Due to environmental factors and malnutrition the number of registered urinary tract cases continuously increases. Most of the methods currently used for urine analysis are expensive, quite laborious and require skilled personnel. The present work deals with feasibility study of potentiometric multisensor system of 18 ion-selective and cross-sensitive sensors as an analytical tool for determination of urine ionic composition. In total 136 samples from patients of Urolithiasis Laboratory and healthy people were analyzed by the multisensor system as well as by capillary electrophoresis as a reference method. Various chemometric approaches were implemented to relate the data from electrochemical measurements with the reference data. Logistic regression (LR) was applied for classification of samples into healthy and unhealthy producing reasonable misclassification rates. Projection on Latent Structures (PLS) regression was applied for quantitative analysis of ionic composition from potentiometric data. Mean relative errors of simultaneous prediction of sodium, potassium, ammonium, calcium, magnesium, chloride, sulfate, phosphate, urate and creatinine from multisensor system response were in the range 3-13% for independent test sets. This shows a good promise for development of a fast and inexpensive alternative method for urine analysis.

dc.title

value: Article


title: Economic fourth order three-stage method for solving systems of second order differential equations with special structure

dc.contributor.author

value: Olemskoy, Igor Vladimirovich

value: Firyulina, Oksana Sergeevna

value: Eremin, Alexey Sergeevich

value: Nechiporuk, Alexey A

dc.description.abstract

value:
An explicit embedded pair of methods for systems
of second order ordinary equations with special structure is
considered. Two-parametric families of methods of orders four
and three with automatic step-size control are constructed. The
numeric comparison to known embedded Runge–Kutta pairs of
the same order is held

dc.publisher

value: Institute of Electrical and Electronics Engineers

dc.subject

value: Runge-Kutta methods, differential equation


title: The interception problem of a celestial body with the use of the collinear libration points

dc.contributor.author

value: Shmyrov, Alexander S.

value: Shymanchuk, Dzmitry

value: Sokolov, Leonid L.

dc.description.abstract

value: This paper studies the problem of an intercept trajectory construction when using the neighborhood of the collinear libration point L1 of the Sun-Earth system. A celestial body motion is considered in a rotating frame within the Hill's problem of the circular restricted three-body problem. It is known that collinear libration points are unstable but its instability can be used as a positive factor for maneuvering a celestial body in the near-Earth space. Development methodology of control algorithms for the orbital motion of a celestial body when using the instability of collinear libration points is offered. The construction of an intercept trajectory is based on the properties of a specially introduced phase variables function, called 'hazard function'. The results of the numerical integration are graphically illustrated. © 2015 IEEE.

dc.language.iso

value: en

dc.publisher

value: Institute of Electrical and Electronics Engineers Inc.


title: Exponential Estimates for Solutions of Linear Systems with Distributed Delay

dc.contributor.author

value: Medvedeva, Irina V.

dc.description.abstract

value: In this paper, for a class of linear time-invariant systems with distributed delay, the robust stability conditions are obtained, and the exponential estimates for the solutions are constructed. The results are derived within the framework of the Lyapunov–Krasovskii functionals with a given derivative. The functional, that does not admit a quadratic lower bound and therefore is considered to be inappropriate for the robustness analysis, is used.

dc.title

filename: Final version.pdf


title: Dynamic model of space robot manipulator

dc.contributor.author

value: Efimova, Polina

dc.description.abstract

value: In this study the dynamic model of a space robot manipulator is constructed. The space robot manipulator as a three-degree-of-freedom manipulator on a movable base is represented. Functional performance of space robotic manipulator near the orbital space station is considered. It is also anticipated that the motion occurs in a weightless environment without affecting the dissipative forces. Based on this model of space robot manipulator the first problem of manipulator dynamics is solved. The problem is solved using the expansion pack Symbolic Math Toolbox of mathematical package Matlab. © 2015 Polina Efimova and Dzmitry Shymanchuk.

dc.publisher

value: Hikari Ltd.


dc.contributor.author

value: Олемской, Игорь Владимирович

value: Еремин, Алексей Сергеевич

value: Иванов, Анатолий Петрович

value: Фирюлина, Оксана Сергеевна

dc.identifier.citation

value: Олемской И.В., Еремин А. С., Иванов А.П., Фирюлина О.С. Экономичный метод шестого порядка интегрирования систем дифференциальных уравнений. В кн.: Устойчивость и процессы управления: Материалы III межд. конф. (СПб, 5 – 9 октября 2015 г.). СПб.: Издательский Дом Федоровой Г.В., 2015. С. 137–138

dc.description.abstract

value: В развитие алгоритмического использования структурных особенностей при конструировании одношаговых методов численного интегрирования систем обыкновенных дифференциальных уравнений  специального вида в статье получена шестиэтапная расчетная схема шестого порядка типа Рунге-Кутты, преодолевающая барьер Бутчера  - m > p, при  p > 4, где m -  число этапов, p - порядок метода.

dc.language.iso

value: ru

value: Устойчивость и процессы управления

dc.type

value: Article

filename: Олемской_Еремин_Фирюлина_Иванов.pdf


dc.contributor.author

value: Квитко, Александр Николаевич

value: Фирюлина, Оксана Сергеевна

value: Таран, Тимофей Стефанович

dc.identifier.citation

value: Квитко А.Н., Таран Т. С., Фирюлина О.С. Наблюдатель типа Люенбергера в решении задачи управления с неполной информацией. В кн.: Устойчивость и процессы управления: Материалы III межд. конф. (СПб, 5 – 9 октября 2015 г.). СПб.: Издательский Дом Федоровой Г.В., 2015. С. 125-126

dc.description.abstract

value: Работа посвящена построению асимптотического наблюдателя пониженного порядка при решении задачи терминального управления для нелинейных управляемых систем с учетом неполной информации

dc.publisher

value: Устойчивость и процессы управления

dc.title

filename: Квитко_Таран_Фирюлина.pdf

description: Основная статья


title: Automated procedure for determination of ammonia in concrete with headspace single-drop micro-extraction by stepwise injection spectrophotometric analysis

dc.contributor.author

value: Timofeeva, Irina I.

value: Khubaibullin, Ilnur I.

value: Kamencev, Mikhail Ya.

value: Moskvin, Alexey L.

value: Bulatov, Andrey V.

dc.description.abstract

value:
A novel automatic stepwise injection headspace single-drop micro-extraction system is
proposed as a versatile approach for automated determination of volatile compounds. The system
application is demonstrated for ammonia determination in concrete samples. An ammonia gas
was produced from ammonium ions and extracted on-line into 5 L 0.1 M H3PO4 to eliminate the
interference effect of concrete species on the ammonia stepwise injection spectrophotometric
determination. The linear range was 0.1 to 1 mg kg-1 with LOD 30 μg kg-1. The sample
throughput was 4 h 1. This system has been successfully applied for the determination of
ammonia in concretes.

dc.description.sponsorship

value:
The authors are grateful to the Russian Foundation for Basic Research for financial
support (project no. 13-03-00031-a).

dc.publisher

value: Elsevier

dc.relation.ispartofseries

value: Talanta;Vol. 133

dc.subject

value: Headspace single-drop micro-extraction

value: Stepwise injection analysis

value: Ammonia

value: Concrete

filename: Talanta 2015_V133.docx


dc.contributor.author

value: Stashkova, Anastasiya E.

value: Peshkova, Maria A.

value: Mikhelson, Konstantin N.

dc.identifier.citation

value: 2.	A.E. Stashkova, M.A. Peshkova, K.N. Mikhelson, Single-ion activity: optical sensing vs. electrochemical sensing, Sensors and Actuators B 207 (2015) 346–350

dc.description.abstract

value:
An approach is proposed aimed at sensing single ion activities with ionophore-based bulk
optodes. The approach relies on the stabilization of the Galvani potential difference at the
optode/sample interface, e.g. by use of tetrabutylammonium tetrabutylborate (Q+B−): a moderately
lipophilic electrolyte used in solid reference electrodes. The pH/Na optode is successfully utilized as a
model system. Optodes modified with Q+B− show

dc.language.iso

value: en

dc.publisher

value: Elsevier Science Publishers

value: optodes

value: individual ion activity

dc.title

format: Microsoft Powerpoint XML


title: Maneuvering in near-Earth space with the use of the collinear libration points

dc.contributor.author

value: Shmyrov, Alexander S.

value: Shymanchuk, Dzmitry

dc.description.abstract

value: The use of the neighborhood of collinear libration point (L1 or L2) of the Sun-Earth system has long been of practical importance in connection with projects implemented by NASA and ESA. A celestial body motion is considered in a rotating frame within the Hill's problem of the circular restricted three-body problem. It is known that collinear libration points are unstable but its instability can be used as a positive factor for maneuvering a celestial body in the near-Earth space. For example, it may be used to solve the problem of comet and asteroid hazard to monitor space objects posing threat to the Earth. We offer a methodology for constructing control algorithms for the orbital motion of a celestial body. This methodology is based on the properties of a specially introduced phase variables function called hazard function. Numerical simulation results are given. © 2015 IEEE.

dc.publisher

value: Institute of Electrical and Electronics Engineers Inc.

dc.type

value: Article


title: Control problem with incomplete information

dc.contributor.author

value: Kvitko, Alexander Nikolaevich

value: Firyulina, Oksana Sergeevna

value: Taran, Timothey

dc.description.abstract

value: By constructing a Luenberger-type asymptotic observer, a method of finding the control function, that ensures the translation of a class of nonlinear stationary control systems of ordinary differential equations from the initial state to a given final state taking into account the actual measured values, was developed. A constructive criterion guaranteeing the existence of solution of this problem was found. An algorithm is proposed for constructing a control function that transfer wide class of nonlinear systems of ordinary differential equations from an initial state to an fixed state. The algorithm is convenient for numerical implementation. A constructive condition is obtained for which this transfer is possible

dc.publisher

value: Institute of Electrical and Electronics Engineers

dc.subject

value: Differential equations, nonlinear control systems, observers, transfer functions


title: Modeling and control of robot manipulators with the constraints at the moving objects

dc.contributor.author

value: Kulakov, Felix M.

value: Alferov, Gennadiy V.

value: Efimova, Polina

value: Chernakova, Svetlana E.

dc.description.abstract

value: In this paper a method of constructing a model of control over compliant motion of robot manipulators is considered. In this method the elastic deformations of flexible manipulators elements are used as feedback signals. © 2015 IEEE.


title: Применение модифицированного алгоритма LSH для кластеризации внешнего окружения веб-пространства университетов

dc.contributor.author

value: Блеканов, Иван

value: Сергеев, Сергей

value: Корелин, Василий

dc.description.abstract

value:
В работе проводится кластерный анализ внешних ресурсов сайтов крупных университетов. В качестве исследуемых объектов были выбраны сайты университетов России, США и Великобритании, занимающие в своих регионах ведущие позиции в вебометрическом рейтинге. Цель работы заключалась в выявлении для каждого сайта университета групп внешних веб-ресурсов с одинаковым родом деятельности. Проводился анализ найденных групп: определялась степень влияния количества и размеров этих групп на вебометрический рейтинг сайтов университетов.
Для достижения поставленной цели авторами разработан алгоритм кластеризации, основанный на вероятностном методе понижения размерности многомерных данных (Locality-Sensitive Hashing – LSH). В работе ставился эксперимент, в котором на тестовых данных было показано, что алгоритм позволяет с высокой скоростью и допустимой точностью проводить кластеризацию большого объема данных. В заключении приводятся основные результаты исследования.

dc.language.iso

value: ru

dc.publisher

value: НАУЧНО-ТЕХНИЧЕСКИЕ ВЕДОМОСТИ САНКТ-ПЕТЕРБУРГСКОГО ГОСУДАРСТВЕННОГО ПОЛИТЕХНИЧЕСКОГО УНИВЕРСИТЕТА. ИНФОРМАТИКА. ТЕЛЕКОММУНИКАЦИИ. УПРАВЛЕНИЕ

dc.title

filename: Применение модифицированного алгоритма LSH.pdf


title: Physico-chemical properties of the water-soluble C70-tris-malonic solutions

dc.contributor.author

value: Manyakina, Olga S.

value: Semenov, Konstantin N.

value: Charykov, Nikolay A.

value: Ivanova, Natalia M.

value: Keskinov, Viktor A.

value: Sharoyko, Vladimir V.

value: Letenko, Dmitrii G.

value: Nikitin, Vladimir A.

value: Klepikov, Vyacheslav V.

value: Murin, Igor V.

dc.description.abstract

value: The paper presents some data on physico-chemical study of the C70-carboxyfullerene water solutions. The data on temperature dependence of solubility in water, concentration dependence of density, specific conductivity, molar conductivity, dissociation constant, and dynamic light scattering are presented and characterized; composition of equilibrium solid phase in binary C70-carboxyfullerene + water system is determined.

dc.language.iso

value: en

dc.publisher

value: Elsevier Science Publishing Company, Inc.

dc.subject

value: Carboxylated fullerene; Solubility; Refractometry; Specific conductivity; Molar conductivity; Dissociation constant

filename: C70 tris-malonate.pdf

description: Статья


title: PHYSICO-CHEMICAL PROPERTIES OF THE C60-ARGININE WATER SOLUTIONS

dc.contributor.author

value: SHESTOPALOVA, A.A

value: KESKINOV, V.A.

value: KLEPIKOV, V.V.

value: SEMENOV, K.N.

value: CHARYKOV, N.A.

value: POSTNOV, V.N.

value: IVANOVA, N.M.

value: SHAROYKO, V.V.

value: MURIN, I.V.

value: LETENKO, D.G.

value: NIKITIN, V.A.

dc.description.abstract

value: The paper presents experimental data on physico-chemical study of the C60-arginine derivative water solutions. The data on temperature dependence of solubility in water, concentration dependence of density, specific conductivity, molar conductivity, dissociation constant, and dynamic light scattering are presented and characterized.

value: Fullerene; Arginine; Solubility; Refractometry; Specific conductivity; Molar conductivity; Dissociation constant

dc.type

value: Article

description: Основная статья


title: Web-based Framework and Search Engine Analytics for Thematic Virtual Museums

dc.contributor.author

value: Blekanov, Ivan

value: Sajarwo, Anggai

value: Sergeev, Sergey

dc.description.abstract

value:
Web is the most powerful platform to handle time, distance and space limitation in physical museum institutions. Based on recent web technology, we have been design web pages more responsive, interactive and dynamic. Web framework is designed to develop dynamic website which have a good structure, providing common library, URL mapping, session and security again attacker, database manipulation, template to generating textual output, light-weight, and often providing concept Model-View-Controller (MVC). Thematic Virtual museums system has been developing based on Go Language web programming because we are pay for attention to the performance. A language which suitable for modern computing infrastructure, light on the page, good on networking and multiprocessing.
In the future development process, thematic virtual museum will be built on two sides they are from curator and visitor side. Curator will be able to provide or display a visualization of interactive contents and exhibitions with the help of analytics software that will be integrated in this framework. As our work in development of Virtual Museum in Indonesia as instrumental for supporting the achievement of the museum functions as a whole.
Thematic virtual museum will be providing Data Access Layer (DAL) or Application Programming Interface (API) for integrating and accessing data sources in museum institutions. This engine working to extracting and obtain relevant information from data sources, designing to understand structure data in current database or semantically tagged of museum institutions where they used to store collections information, and system also support to manage unstructured data that have not define data-model or semantic.
In this paper, we have informed our progress about development web-based framework using Go Language for thematic virtual museums, concept and design of Search Engine Analytics as a core of this system to provide closest information to the visitors align with the approach of thematic virtual museum which can be used to process data or information inside museum institutions.

dc.language.iso

value: en

dc.publisher

value: IEEE Proceedings of the 2015 4th International Conference on Interactive Digital Media (ICIDM), IEEE


title: Теоретико-графовые характеристики в вебометрических исследованиях внутренней топологии крупных сегментов Веба

dc.contributor.author

value: Блеканов, Иван

value: Москалец, Роман

dc.publisher

value: Процессы управления и устойчивость

filename: Теоретико-графовые характеристики в вебометрических исследованиях.pdf


title: Индекс для обработки и хранения гиперссылочных структур крупных Веб-сегментов

dc.contributor.author

value: Блеканов, Иван

value: Нархов, Семен

dc.description.abstract

value: Процессы управления и устойчивость

filename: Индекс для обработки и хранения гиперссылочных структур.pdf


title: Hierarchical clustering of large text datasets using Locality-Sensitive Hashing

dc.contributor.author

value: Blekanov, Иван

value: Korelin, Vasilii

value: In this paper, we present a hierarchical clustering algorithm of the large text datasets using Locality-Sensitive Hashing (LSH). The main idea of the LSH is to “hash” items several times, in such a way that similar items are more likely to be hashed to the same bucket than dissimilar are. The main drawback of the conventional hierarchical algorithms is a large time complexity (e.g. Single Linkage method has time complexity of O(n^2)) Proposed algorithm reduces the time complexity to O(Pn). Here, P represents the maximum number of items going to the single bucket. P is a small constant as compared to n for the large number of buckets.

dc.publisher

value: Proceedings of the International Workshop on Applications in Information Technology (IWAIT-2015)

dc.title

filename: Clustering using LSH eng v1.pdf


dc.contributor.author

value: Sergeev, Sergei

value: Klemeshov, Evgenii

dc.description.abstract

value: This paper presents experimental results on websites of four universities investigated with the aim of drawing up lists of pages and links. Variants of functions approximating the experimental data are considered. The resulting approximation estimates indicate that the approximating functions proposed are of high precision.

filename: Study of patterns in the hyperlink structure of large sites.pdf


title: Regio- and stereoselective 1,3-dipolar cycloaddition of cyclic azomethine imines to platinum(IV)-bound nitriles giving Δ2-1,2,4-triazoline species,

dc.contributor.author

value: Smirnov, Andrey S.

value: Kritchenkov, Andrey S.

value: Bokach, Nadezhda A.

value: Selivanov, Stanislav I.

value: Gurzhiy, Vladislav V.

value: Kuznetsov, Maksim L.

value: Roodt, Andreas

value: Kukushkin, Vadim Yu.

value: The complex trans-[PtCl4(EtCN)2] (14) reacts smoothly at RT with the stable cyclic azomethine imines R1CH=NaNC(O)CH(NHC(O)C6H4R3)CbH(C6H4R2)(a−b) [R1/R2/R3 = p-Me/H/H (8); p-Me/p-Me/H (9); p-Me/p-MeO/H (10); p-Me/p-Cl/p-Cl (11); p-MeO/p-Me/(H) (12); p-MeO/p-Cl/m-Me (13)] and the reaction proceeds as stereoselective 1,3-dipolar cycloaddition to one of the EtCN ligands accomplishing the mono-cycloadducts trans-[PtCl4(EtCN){Na=C(Et)NbC(O)CH(NHC(O)C6H4R3)CH(C6H4R2)NcCdHR1}])(a–d;b–c) [R1/R2/R3 = p-Me/H/H (15); p-Me/p-Me/H (16); p-Me/p-MeO/H (17); p-Me/p-Cl/p-Cl (18); p-MeO/p-Me/H)(19); p-MeO/p-Cl/m-Me (20)]. Inspection of the obtained and literature data indicate that the cycloaddition of the azomethine imines to the C≡N bonds of HCN and of PtIV-bound EtCN has different regioselectivity leading to Δ2-1,2,3-triazolines and Δ2-1,2,4-triazolines, respectively. Platinum(II) species trans-[PtCl2(EtCN){Na=C(Et)NbC(O)CH(NHC(O)C6H4R3)CH(C6H4R2)NcCdHR1}](a–d;b–c) [R1/R2/R3 = p-Me/H/H (21); p-Me/p-Me/H (22); p-Me/p-MeO/H (23); p-Me/p-Cl/p-Cl (24); p-MeO/p-Me/H (25); p-MeO/p-Cl/m-Me (26)] were obtained by one-pot procedure from 14 and 8–13 followed by addition of the phosphorus ylide Ph3P=CHCO2Me. Δ2-1,2,4-Triazolines Na=C(Et)NbC(O)CH(NHC(O)C6H4R3)CH(C6H4R2)NcCdHR1(a–d;b–c) [R1/R2/R3 = p-Me/H/H (27); p-Me/p-Me/H (28); p-Me/p-MeO/H (29); p-Me/p-Cl/p-Cl (30); p-MeO/p-Me/H (31); p-MeO/p-Cl/m-Me (32)] were liberated from 21–26 by the treatment with dppe. Platinum(II) complexes 21–26 were characterized by elemental analyses (C, H, N), high-resolution ESI-MS, and IR and 1H and 13C{1H} NMR spectroscopies and single crystal X-ray diffraction in solid state for 25•CH3OH, 26•(CHCl3)0.84. The structure of 26 was also determined by COSY-90 and NOESY NMR methods in solution. Quantitative evaluation of several pairs of interproton distances obtained by NMR and XRD agrees well with each other and with those obtained by the MM+ calculation method. Platinum(IV) complexes 15–20 were characterized by 1H NMR spectroscopy. Metal-free 6,7-dihydropyrazolo[1,2-a][1,2,4]triazoles (27−32) were characterized by high-resolution ESI-MS, and IR and 1H and 13C{1H} NMR spectroscopies and single crystal X-ray diffraction for 29•CDCl3. Theoretical DFT calculations were carried out for the investigation of the reaction mechanism, interpretation of the reactivity of Pt-bound and free nitriles toward azomethine imines and analysis of the regio- and stereoselectivity origin.

dc.publisher

value: ACS

dc.relation.ispartofseries

value: Inorganic Chemistry;54

dc.subject

value: 1,3-dipolar cycloaddition

dc.title

filename: Graphical Abstracts.docx


title: Click-type PtII-mediated hydroxyguanidine–nitrile coupling provides useful catalysts for hydrosilylation cross-linking

dc.contributor.author

value: Demakova, Marina Ya.

value: Bolotin, Dmitrii S.

value: Islamova, Regina M.

value: Starova, Galina L.

dc.description.abstract

value: The nitrile complexes trans-[PtCl2(RCN)2] (R = Et NC1, tBu NC2, Ph NC3, p-BrC6H4 NC4) and cis-[PtCl2(RCN)2] (R = Et NC5, tBu NC6, Ph NC7) react with 1 equiv of the hydroxyguanidine OC4H8NC(=NOH)NH2 (HG) furnishing the mono-addition products cis- and trans-[PtCl2(RCN){NH=C(R)ON=C(NH2)NC4H8O}] (1–4 and 9–11; 7 examples; 54–74%). Treatment any one of NC1–NC7 with HG in a 1:2 molar ratio about generation of the bis-addition products cis- and trans-[PtCl2{NH=C(R)ON=C(NH2)NC4H8O}2] (5–8 and 12–14; 7 examples; 69–89%). The PtII-mediated coupling between nitrile ligands and HG proceeds substantially faster than the relevant reactions involving amid- and ketoximes and gives redox stable products under normal conditions. All new complexes 1–14 and previously unreported NC4 were characterized by elemental analyses (C, H, and N), IR, high resolution ESI-MS, 1H and 13C{1H} NMR spectroscopies. Complexes 1, 6•4CH2Cl2, 7•4CH2Cl2, 8•2CH2Cl2, and NC4 were studied by X-ray crystallography. Platinum(II) species 1–3, 10–11, and especially 9, efficiently catalyze hydrosilylation cross-linking of vinyl terminated poly(dimethylsiloxane) and trimethylsilyl terminated poly(dimethylsiloxane-co-ethylhydrosiloxane) giving high quality thermally stable silicon resins with no structural defects. The usage of these platinum species as the catalysts do not require any inhibitors and, moreover, the complexes and their mixtures with vinyl- and trimethylsilyl terminated polysiloxanes are shelf-stable in air.

dc.language.iso

value: en

dc.publisher

value: Wiley

dc.subject

value: hydrosilylation

dc.type

value: Article


title: Highly reactive NiII-bound nitrile–oxime coupling intermediate stabilized by substituting conventional nitriles with a dialkylcyanamide

dc.contributor.author

value: Andrusenko, Elena V.

value: Kabin, Evgenii V.

value: Novikov, Aleksander S.

value: Bokach, Nadezhda A.

value: Zolotarev, Andrey A.

dc.description.abstract

value: Nickel(II)-mediated coupling between the cyanamide Me2NCN and the ketoximes Me(R)C=NOH (R = Me, Ph) gives chelates of the general formula [NiClx(H2O)y{HN=C(NMe2)ON=C(R)Me)}2]n+ ([1]+: R = Me; x = 1; y = 0, salts with both Cl– and [NiCl4]2– were isolated; [2]2+: R = Me, x = 0; y = 2, salt with Cl– was isolated; [3]+: R = Ph, x = 1; y = 1, salt with Cl– was isolated) and the iminium salts [H2N=C(NMe2)ON=C(R)Me]+ ([4]+: R = Me, salt with [NiCl4]2– was isolated; [5]+: R = Ph, salt with Cl– was isolated). This reaction demonstrates the difference in the reactivity between conventional nitriles and dialkylcyanamides, viz. if RCN (R = Alk, Ar) react with NiII/ketoxime system achieving (1,3,5-triazapentadiene)NiII species, formed via postulated nitrile–oxime coupling intermediate, the cyanamide under the same conditions gives either stable cyanamide–oxime coupling products or the Busch’s type complex [Ni{HN=C(Me)CH2C(Me2)NH2}2]Cl2 ([6]Cl2). Complexes [1]Cl, [2]Cl2•H2O, [3]Cl, and [6]Cl2 were characterized by elemental analyses (C,H,N), high resolution ESI+-MS, IR, DTA/TG, and also by X-ray crystallography. Compounds [1]2[NiCl4], [4]2[NiCl4], and [5]Cl were identified by single-crystal X-ray diffraction. The reason of different stability of the coupling products was interpreted theoretically based on the quantum chemical calculations (M06-L/6-31G* level of theory). The NMe2 moiety in the chelate ligands leads to an increase in electron density delocalization and also stabilize the systems in terms of electrostatic causes.

dc.relation.ispartofseries

value: European Journal of Inorganic Chemistry;2015

dc.subject

value: ligand reactivity

dc.title

format: Unknown


title: Facile zinc(II)-mediated generation of 5-amino substituted 2,3-dihydro-1,2,4-oxadiazoles and their further ZnII-catalyzed and O2-involving transformations, New J. Chem., 39 (2015) 9330–9344, DOI: 10.1039/C5NJ02061A

dc.contributor.author

value: Smirnov, Andrey S.

value: Butukhanova, Ekaterina S.

value: Gurzhiy, Vladislav V.

value: Kukushkin, Vadim Yu.

dc.description.abstract

value: ZnII-activated cyanamides NCNR2 (R2 = Me2, Et2, C5H10, C4H8O, Ph2) react with the acyclic N-alkyl ketonitrones Ph2C=N+(O–)R’ (R’ = Me, CH2Ph) and N-aryl ketonitrones (R’ = Ph, p-BrC6H4, p-EtC6H4) under mild conditions. Uncomplexed 5-aminosubstituted 2,3-dihydro-1,2,4-oxadiazoles (6 examples; 49–82%) were obtained in zinc(II)-involving cycloaddition of the N-alkyl ketonitrones to the cyanamide substrates; these 2,3-dihydro-1,2,4-oxadiazoles undergo ring-opening giving carbamoylamidines and methylidenureas. The N-aryl ketonitrones react with ZnII-activated cyanamides giving the open-chain systems, viz. carbamoylamidines, N'-(2-(diphenylmethylidene)amino)-phenyl-N,N-carbamimidic acids, and methylidenureas, which are presumably formed via the cycloaddition route followed by the N–O cleavage induced by the acceptor character of the aryl groups.

dc.publisher

value: RSC

dc.relation.ispartofseries

value: New Journal of Chemistry;39


title: Metal-mediated and metal-catalyzed reactions of isocyanides

dc.contributor.author

value: Boyarskiy, Vadim P.

value: Luzyanin, Konstantin V.

dc.description.abstract

value: isocyanides

dc.language.iso

value: en

dc.publisher

value: ACS

value: Chemical Reviews;vol. 115

dc.subject

value: transition metals

value: catalysis

dc.title

format: RTF


title: Bifunctional reactivity of amidoximes observed upon nucleophilic addition to metal-activated nitriles

dc.contributor.author

value: Bolotin, Dmitrii S.

value: Demakova, Marina Ya.

value: Novikov, Aleksander S.

value: Avdontceva, Margarita S.

value: Kuznetsov, Maxim L.

value: Bokach, Nadezhda A.

dc.description.abstract

value: Treatment of the aromatic nitrile complexes trans-[PtCl2(RC6H4CN)2] (R = p-CF3 1, H 2, o-Cl 3) with the aryl amidoximes p-R’C6H4C(NH2)=NOH (R’ = Me 4, H 5, Br 6, CF3 7, NO2 8) in all combinations, followed by addition of 1 equiv of AgOTf and then 5 equiv of Et3N leads to the chelates [PtCl{HN=C(RC6H4)ON=C(C6H4R’-p)NC(RC6H4)=NH}] (9–23; 15 examples; yields 71–88% after column chromatography) derived from the platinum(II)-mediated coupling between metal-activated nitriles and amidoximes. The mechanism of this reaction was studied experimentally by trapping and identification of the reaction intermediates and it was also investigated theoretically at the DFT level of theory. The combined experimental and theoretical results indicate that the coupling with the nitrile ligands involves both the HON and monodeprotonated NH2 groups of the amidoximes, whereas in the absence of the base, the NH2 functionality is inactive toward the coupling. The observed reaction represents the first example of bifunctional nucleophilic behavior of amidoximes. The complexes 9–24 were characterized by elemental analyses (C, H, N), high resolution ESI+-MS, FTIR, 1H NMR techniques, whereas unstable 25 was characterized by HRESI+-MS and FTIR. In addition, 16•C4H8O2, 20, and 24•CHCl3 were studied by single-crystal X-ray diffraction.

dc.relation.ispartofseries

value: Inorganic Chemistry;vol. 54

dc.subject

value: nucleophilic addition

value: nitriles

dc.type

value: Article

filename: Graphical Abstracts.pdf


title: Metal-mediated cyanamide–hydroxyguanidine coupling

dc.contributor.author

value: Starova, Galina L.

value: Kukushkin, Vadim Yu.

dc.description.abstract

value: Reaction of the cyanamides R2NCN (R = Me 2a, Et 2b) with the hydroxyguanidine OC4H8NC(=NOH)NH2 (1) in the presence of zinc halides leads to [ZnX2{HN=C(NR2)ON=C(NH2)NC4H8O}] derived from the ZnII-mediated cyanamide–hydroxyguanidine coupling. This reaction is the first observation of interplay between any nitrile group and any hydroxyguanidine both in metal-involving and metal-free chemistry. Complexes 3a,b–5a,b rather rapidly degrade in solutions at RT, but solvates 3a,b•MeOH and 4a•MeOH are sufficiently stable in the solid state and they were characterized by IR, HRESI+-MS, solid state CP-MAS TOSS 13C NMR, and X-ray crystallography (for 3a,b). Complexes 4b and 5a,b were identified in solutions by HRESI+-MS.

dc.publisher

value: Elsevier

dc.relation.ispartofseries

value: Inorganica Chimica Acta;425

dc.subject

value: Hydroxyguanidine

value: Cyanamide

value: Zinc(II) complexes

value: Metal-mediated reaction


title: Мировое соглашение как задача гражданского судопроизводства

dc.contributor.author

value: Крюков, Д.В.

dc.description.abstract

value: This article rises the problem of importance of institute of amicable agreement and its necessity in civil procedure, and it reveals the legal nature of this legal mechanism of resolving litigation. The article images the reasons for which court should input its efforts during civil investigation in order to settle parties for the amicable agreement. In the overwhelming majority of cases, litigation concludes with the judgment in favor of one of the parties, which affirms that the defeated party will not be satisfied with the results of the procedure. In addition, due to the author’s opinion, the court should aim to not only adopt accurate, reasonable and founded in law litigation, but also should normalize the relations between participants of civil law relationship to mutual satisfaction of their interests, because it will promote the stabilization of civil procedure and establish the priority of cooperation between parties, not their confrontation.

dc.title

size: 35 kB


title: Does corporate language influence career mobility? Evidence from MNCs in Russia

dc.contributor.author

value: Latukha, Marina O.

value: Doleeva, Anna

value: Järlström, Maria

value: Jokinen, Tiina

value: Piekkari, Rebecca

dc.description.abstract

value: The paper investigates how corporate language influences the career mobility of MNC employees in Russia. We apply human capital theory to show how language may be valued in an organizational context. In our work we use a framework that demonstrates that corporate language may act as a glass ceiling. The results show that employees in Russian MNCs with a lower level of corporate language skills will be less likely to consider vertical and horizontal career mobility than employees with a higher level of these language skills. Equally, employees in Russian MNCs with a lower level of corporate language skills will be less likely to consider internal and external career mobility than those employees with a higher level of these language skills. We prove that corporate language may act both as a barrier and as a facilitator for the career mobility of employees in Russian MNCs who have different levels of corporate language skills.

dc.description.sponsorship

value: The authors gratefully acknowledge the financial support granted by the Foundation for Economic Education, and the support of the Center for the Study of Emerging Market and Russian Multinational Enterprise (project ID 15.61.172.2015).

dc.language.iso

value: English

dc.relation.ispartofseries

value: European Management Journal;Available online 13 January 2016

dc.subject

value: corporate language

value: language skills

value: career mobility

value: career development

value: multinational corporations

value: Russia

filename: Latukha_Does corporate language influence career mobility.pdf


title: Масс-медиа и консолидация «Русского мира»

dc.contributor.author

value: Ачкасова, Вера А

value: Смолярова, Анна С

dc.description.abstract

value:
В статье рассматриваются проблемы функционирования русскоязычных масс-медиа в государствах
постсоветского пространства. Основное внимание уделяется той роли, которую могли бы сыграть русскоязычные
СМИ в процессе консолидации «Русского мира» и поддержке русской диаспоры.

dc.language.iso

value: ru

dc.publisher

value: Межпарламентская Ассамблея Евразийского экономического сообщества

value: Русскоязычные масс-медиа; постсоветское пространство; «Русский мир»; диаспора; консолидация сооте- чественников

dc.title.alternative

value: Mass Media and «Russian World» Consolidation

dc.type

value: Article

filename: Ачкасова, Смолярова_Евразийская интеграция_2015.pdf


title: The Ecclesiastical History of Gelasius of Cyzicus and the Campaign of Constantine the Great against Maxentius in 312 A.D.: on the Establishment of Late Roman Military Rank auxilia palatina

dc.contributor.author

value: Mekhamadiev, Evgeniy A.

dc.description.abstract

value: The main problem of research on the military reforms initiated by the Emperor Constan-tine I (306–337 A.D.) is that it is hard to trace differences between the legal status and rank of military units established by this ruler. All the sources most frequently cited by the scholars (Eusebius of Caesarea, Zosimus, Latin Panegyrics), unfortunately, specify nothing on the origin and titles of all the detachments, which fought together with Constantine against Maxentius and Licinius, his main rivals. In this respect, the data provided by Gelasius of Cyzicus in his neglected Ecclesiastical History may clarify some aspects of this problem despite that the text itself was published as early as 1918. However, this source has not drawn attention of the scholars, who traditionally relied on more famous ancient writers. On the basis of Gelasius’ evidence, the origin of military units, which received the title of auxilia palatina in the Late Roman military hierarchy, was considered in this paper. Solution to the discussed problem is directly associated with the involvement and role of the German tribes in Constantine’s army. The evidence presented by Gelasius help to understand the kinds of this involvement and how differences in service influenced the formation of auxilia palatina rank.

value: Главная проблема, возникающая при изучении военных реформ императора Кон-стантина I (306–337 гг.), состоит в том, что крайне трудно проследить и установить чет-кие различия в правовом положении и ранге тех войсковых соединений, которые были созданы Константином в ходе его многочисленных войн. Все источники, наиболее часто попадающие в поле зрения исследователей (произведения Зосима, Евсевия Кесарийского, латинские панегирики), к сожалению, ничего не сообщают о происхождении и названиях (технических, официальных наименованиях) военных отрядов, служивших в армии Кон-стантина. В этом плане сведения восточноримского (ранневизантийского) церковного историка Геласия Кизикийского, незаслуженно обойденного вниманием и находящегося в тени своих более именитых коллег (Сократ Схоластик, Гермий Созомен, Феодорит Киррский), могут пролить свет на все поставленные вопросы, внести в их решение опре-деленную новизну и в то же время ясность. Примечательно, что сам текст источника («Церковной истории», главного и единственного произведения Геласия, дошедшего до наших дней) был введен в оборот еще в 1918 г. публикацией Г. Лешке, но вплоть до наших дней исследователи не привлекали эти сведения в военном контексте. На основе данных Геласия автор рассматривает происхождение войсковых соединений, обладав-ших рангом auxilia palatina, – эти отряды несли службу во дворце императора и были самыми привилегированными в военной иерархии поздней Римской империи.

dc.publisher

value: Kazan State University

dc.relation.ispartofseries

value: Uchenye Zapiski Kazanskogo Universiteta. Humanities;Vol. 157, Issue 3

dc.subject

value: Gelasius of Cyzicus

value: the Germans

value: Геласий с Кизика

value: Германцы

value: legion

value: легион

value: Constantine I

value: Константин I

value: mercenaries

value: наемники

value: auxiliaries

value: ауксилии

dc.title.alternative

value: «ЦЕРКОВНАЯ ИСТОРИЯ» ГЕЛАСИЯ КИЗИКИЙСКОГО И ПОХОД КОНСТАНТИНА I ВЕЛИКОГО ПРОТИВ МАКСЕНЦИЯ В 312 г.: К ВОПРОСУ ОБ УЧРЕЖДЕНИИ ПОЗДНЕРИМСКОГО ВОЙСКОВОГО РАНГА AUXILIA PALATINA

filename: Мехамадиев-Казань-Геласий.pdf

description: Церковная история Геласия Кизикийского


dc.contributor.author

value: Stepanov, Mikhail

value: Степанов, М.В.

dc.contributor.editor

value: Maltseva, Svetlana V.

value: Stanyukovich-Denisova, Ekaterina Yu.

value: Zakharova, Anna V.

value: Мальцева, С.В.

value: Станюкович-Денисова, Е.Ю.

value: Захарова, А.В.

dc.identifier.citation

value: Mikhail Stepanov. The Reconstruction of Working Methods for Constructing Architectural Forms  Two Temples of the First Half of the 16th Century. Actual Problems of Theory and History of Art: Collection of articles. Vol. 5. Eds: Svetlana V. Maltseva, Ekaterina Yu. Stanyukovich-Denisova, Anna V. Zakharova. St. Petersburg, NP-Print Publ., 2015, pp. 348–357. ISSN 2312-2129. http://dx.doi.org/10.18688/aa155-3-37

value: Степанов М. В. Воссоздание рабочих методов для построения архитектурных форм двух храмов первой половины XVI века // Актуальные проблемы теории и истории искусства: сб. науч. статей. Вып. 5. / Под ред. С.В. Мальцевой, Е.Ю. Станюкович-Денисовой, А.В. Захаровой. – СПб.: НП-Принт, 2015. С. 348–357. ISSN 2312-2129. http://dx.doi.org/10.18688/aa155-3-37

dc.description.abstract

value: The article is dedicated to the review of the erecting process for tower type cult structures in early 16thcentury Russia. Since there are common laws for military, civil and religious architecture, the author is trying to solve the problem by using the erecting method for tower type of civil constructions described by Alberti in the analysis of religious buildings of the same type. The article also contains a detailed study of volumetric composition of the Church of St. John Climacus and the Church of the Ascension in Kolomenskoye village. The author comes to the conclusion that Italian architects of these churches used the method described by Alberti, and that, as evidence shows, they could use some decorative elements from the image of the original façade of the church of Santa Maria del Fiore in their work.

value:
 Статья посвящена реконструкции рабочего метода для древнерусских культовых сооружений башенного типа начала XVI в. Учитывая общность целого ряда технических приемов, используемых при возведении оборонительных, гражданских и культовых построек, автор данного исследования проанализировал характерные особенности рабочих методов, представленных в трактате Альберти, применительно к проблеме изучения практики древнерусских зодчих. В качестве конкретных образцов в статье рассматриваются индивидуальные, специфические особенности объемно-пространственных композиций церкви Иоанна Лествичника в Московском Кремле и церкви Вознесения Господня в селе Коломенском. Предложенный автором новый подход осмысления древних строительных технологий принципиально отличается от традиционного абстрактно-математического анализа, обычно применяемого в изучении памятников архитектуры.

	Теоретический вариант реконструкции рабочего метода, описанного Альберти, показал творческий потенциал, заложенный в этих технологических приемах, которыми, как мы предполагаем, воспользовались итальянские архитекторы в практике строительства на русской почве. Также проведенный анализ позволил выявить и ряд различий, в частности, в способах определения габаритных размеров объемно-пространственной композиции, масштаба декоративных элементов, а также дал возможность иначе интерпретировать термин «на деревянное дело».

dc.language.iso

value: ru

dc.publisher

value: NP-Print

value: НП-Принт

dc.subject

value: proportions

value: Old Russian architecture

value: architectural forms

value: logic of harmony

value: пропорции в архитектуре

value: древнерусское зодчество

value: архитектурные формы

value: логика гармонии

dc.type

value: Article

description: Article

description: Cover


dc.contributor.author

value: Vaniushin, Artem

value: Ванюшин, А.С.

dc.contributor.editor

value: Мальцева, С.В.

value: Станюкович-Денисова, Е.Ю.

value: Захарова, А.В.

dc.identifier.citation

value: Artem Vaniushin. Mediaeval Architecture of the Mendicant Orders in Poland — Origins and Characteristics. Actual Problems of Theory and History of Art: Collection of articles. Vol. 5. Eds: Svetlana V. Maltseva, Ekaterina Yu. Stanyukovich-Denisova, Anna V. Zakharova. St. Petersburg, NP-Print Publ., 2015, pp. 418–425. ISSN 2312-2129. http://dx.doi.org/10.18688/aa155-4-45

value: Ванюшин А. С. Средневековая архитектура нищенствующих орденов в Польше: происхождение и особенности // Актуальные проблемы теории и истории искусства: сб. науч. статей. Вып. 5. / Под ред. С.В. Мальцевой, Е.Ю. Станюкович-Денисовой, А.В. Захаровой. – СПб.: НП-Принт, 2015. С. 418–425. ISSN 2312-2129. http://dx.doi.org/10.18688/aa155-4-45

dc.description.abstract

value:
This article is dedicated to the key features of the formation and development of the medieval architecture of the mendicant orders in Poland. The first part of the 13th century can be considered as the starting point of the emergence of the architecture of Polish Dominicans and Franciscans, since it was the time of arrival of the first members of both orders to Poland. The mendicants could use local Cistercian abbeys as the prototypes for their own buildings characterized by simplified layouts, which reflected so-called “anticathedral” tendencies in church architecture. The churches that were in the possession of the mendicant orders started in part losing their originality after some remodeling caused by the softening
	of the monastic rules of the Dominicans and Franciscans at the end of the 13th century, which made former restrictions inappropriate. The churches belonged to the mendicants in the various parts of Poland could also undergo some changes that led to their integration with local architectural traditions and caused their deviation from the conventional typology. However, Polish Dominican and Franciscan architecture retained its individual features till the end of the Gothic era in the beginning of the 16th century.

value: В статье рассматриваются ключевые особенности формирования и развития архитектуры нищенствующих орденов в Польше. Отправной точкой данного направления в зодчестве является первая половина XIII в., когда первые доминиканцы и францисканцы прибыли на польские земли. Опираясь на образцы архитектуры местных цистерцианцев, монахи нищенствующих орденов создали уникальный тип готической храмовой архитектуры упрощенной планировки, воплотив тем самым так называемые антикафедральные тенденции в зодчестве. После смягчения уставов обоих орденов в конце XIII в. существовавшие ранее строительные ограничения были отменены, что привело к частичной утрате доминиканскими и францисканскими храмами своей самобытности в ходе перестроек. Однако до начала XVI в. под влиянием местных традиций готики архитектура нищенствующих орденов, интегрируясь с локальными традициями зодчества, продолжала сохранять индивидуальные черты.

dc.subject

value: medieval architecture

value: Gothic

value: Polish art

value: Dominicans

value: Franciscans

value: средневековая архитектура

value: готика

value: искусство Польши

value: доминиканцы

value: францисканцы

dc.title.alternative

description: Article

description: Cover


dc.contributor.author

value: Murat, Zuleika

value: Зулейка, Мурат

dc.contributor.editor

value: Maltseva, Svetlana V.

value: Stanyukovich-Denisova, Ekaterina Yu.

value: Zakharova, Anna V.

value: Мальцева, С.В.

value: Станюкович-Денисова, Е.Ю.

value: Захарова, А.В.

dc.identifier.citation

value: Zuleika Murat. The Compendium historiae in Genealogia Christi and its Iconographical Tradition: Legacy of Classical Antiquity in a Mediaeval Biblical Anthology. Actual Problems of Theory and History of Art: Collection of articles. Vol. 5. Eds: Svetlana V. Maltseva, Ekaterina Yu. Stanyukovich-Denisova, Anna V. Zakharova. St. Petersburg, NP-Print Publ., 2015, pp. 404–411. ISSN 2312-2129. http://dx.doi.org/10.18688/aa155-4-43

value: Зулейка Мурат. Compendium Historiae in Genealogia Christi и его иконографическая традиция: наследие античности в средневековой библейской антологии // Актуальные проблемы теории и истории искусства: сб. науч. статей. Вып. 5. / Под ред. С.В. Мальцевой, Е.Ю. Станюкович-Денисовой, А.В. Захаровой. – СПб.: НП-Принт, 2015. С. 404–411. ISSN 2312-2129. http://dx.doi.org/10.18688/aa155-4-43

dc.description.abstract

value: This article aims to analyse a little known, yet extremely important, phenomenon of reception of Сlassical antiquity and its legacy in the Middle Ages. It deals with the Compendium historiae in genealogia Christi, a biblical anthology created at the end of the 12th century by Peter of Poitiers, theologian and teacher at the Cathedral school of Paris. In the prologues, Peter himself declared that the purpose of his work was to help his students to fix in memory the complex biblical material. For this reason the text was written in a simplified and resumptive way, and it was also accompanied by an 15 On this very interesting manuscript see [11, p. 165] and [16, pp. 180–183, no. 21]. unusual apparatus of images that immediately visualized the main concepts which the students should learn and remember. Peter seems to have derived the figurative system from Greek and Roman mnemonic treatises. Through selected case studies, I aim to demonstrate how Сlassical antiquity and its legacy made a contribution in the creation of that specific art system, tracing the connections between ancient theory and mediaeval practice.

value: Данная статья посвящена анализу малоизученного, но тем не менее чрезвычайно значимого феномена восприятия классической античности и ее наследия в Средние века. Объектом исследования является Compendium historiae in genealogia Christi — библейская антология, созданная в конце XII в. Питером из Пуатье, теологом и преподавателем Кафедральной школы в Париже. В прологе сам Питер поясняет, что назначение его книги — помочь студентам с запоминанием сложного библейского материала. По этой причине текст был написан в упрощенной обобщающей манере и сопровождался необычным набором иллюстраций, посредством которых происходила мгновенная визуализация основных понятий, которые студенты должны были усвоить и запомнить. Питер, как полагает автор, мог заимствовать образную систему из греческих и римских мнемонических трактатов. На нескольких примерах продемонстрировано, как наследие классической античности отразилось на создании этой специфической художественной системы, и прослежена связь между античной теорией и средневековой практикой.

dc.language.iso

value: en

dc.publisher

value: NP-Print

value: НП-Принт

dc.subject

value: Peter of Poitiers

value: Compendium

value: Art of Memory

value: Scholastic

value: Cathedral Schools

value: Diagrams

value: Питер из Пуатье

value: компендиум

value: искусство запоминания

value: схоластика

value: Кафедральная школа

value: диаграммы

dc.title

description: Article

description: Cover


dc.contributor.author

value: Doig, Allan

value: Доиг, АлланДжордж

dc.contributor.editor

value: Maltseva, Svetlana V.

value: Stanyukovich-Denisova, Ekaterina Yu.

value: Zakharova, Anna V.

value: Мальцева, С.В.

value: Станюкович-Денисова, Е.Ю.

value: Захарова, А.В.

dc.identifier.citation

value: Allan Doig. Building, Enacting and Embodying Romanitas: the Throne of Charlemagne. Actual Problems of Theory and History of Art: Collection of articles. Vol. 5. Eds: Svetlana V. Maltseva, Ekaterina Yu. Stanyukovich-Denisova, Anna V. Zakharova. St. Petersburg, NP-Print Publ., 2015, pp. 376–382. ISSN 2312-2129. http://dx.doi.org/10.18688/aa155-4-40

value: Доиг Аллан Джордж. Трон Карла Великого в Аахене: римская идея и ее воплощение // Актуальные проблемы теории и истории искусства: сб. науч. статей. Вып. 5. / Под ред. С.В. Мальцевой, Е.Ю. Станюкович-Денисовой, А.В. Захаровой. – СПб.: НП-Принт, 2015. С. 376–382. ISSN 2312-2129. http://dx.doi.org/10.18688/aa155-4-40

dc.description.abstract

value: This paper will explore the development of aspects of the ideological underpinning of Charlemagne’s Renovatio Romani Imperii. The object under inspection will be Charlemagne’s throne in the Basilica at Aachen, and attention will extend to the origin of its materials, its artistic, architectural and ceremonial context, and what it has to tell us about the person and the office of the King-Emperor. Romanitas, in this sense, is a set of ideals projected backwards onto the Christian Roman Empire and its remnants. This vision of Roman identity was made visible in cultural manifestations from daily rituals to art and architecture. Elements of all these had survived the gradual collapse of Roman institutions in the Western Empire. The narrative of the founding of the Christian Empire provided by Eusebius, was explicitly emulated and continued by Gregory of Tours in his History of the Franks, in which he records the elements of the Roman legacy that survived in Merovingian Gaul to the end of the 6th century. With Merovingian royal power exhausted, the Pippinids took the inheritance of these fragments in combination with newly acquired fragments, cultural spolia you might say, and combined them within ecclesiastical and intellectual disciplines from “Rome” itself, to create a renewed Empire in bricolage. The throne will show how this reconstituted romanitas was convincing enough to be mocked (defensively), yet grudgingly admired, and finally recognised by the Emperor in the other “New Rome”.

value: В статье рассматриваются различные аспекты развития идеологической подоплеки каролингского девиза Renovatio Romani Imperii, призывавшего к возрождению Римской империи. В центре внимания автора трон Карла Великого в базилике Аахена — помимо вопроса о происхождении составляющих его материалов анализируется художественный, архитектурный и обрядовый контекст, проливающий свет на личность короля-императора и особенности его правления. Понятие Romanitas в данном случае — это совокупность идеалов, экстраполированных на Позднюю Римскую империю и то, что от нее сохранилось. Самоидентификация с римской имперской идеей разными способами визуально воплощалась как в повседневных ритуалах, так и в изобразительном искусстве и архитектуре. Отдельные элементы целостной концепции, пережив постепенный распад общественных институтов Западной Римской империи, сохранились и в Средние века. Сочинение Евсевия Кесарийского об основании «христианской империи» было решительно поддержано Григорием Турским, а идеи получили развитие в его «Истории франков», где описаны те особенности римского наследия, которые продолжились в меровингской Галлии вплоть до конца VI в. Когда власть династии Меровингов была исчерпана, кое-что из этого наследия усвоили Пипиниды и, соединив его с вновь открытыми фрагментами, так сказать, культурной сполией, а также собственно «римскими» духовными и интеллектуальными принципами, из этих «подручных средств» создали эклектичный концепт обновленной империи. На примере трона в Аахене показано, как возрожденная римская идея, поначалу вызывавшая сомнения и вялое восхищение, в конечном счете была признана императором как идея еще одного «Нового Рима».

dc.subject

value: the Throne of Charlemagne

value: Basilica at Aachen

value: Romanitas

value: Merovings

value: Pippinids

value: Romans

value: Theodoric

value: трон Карла Великого

value: базилика в Аахене

value: Меровинги

value: Пипиниды

value: римляне

value: Теодорих

dc.type

value: Article

description: Article

description: Cover


dc.contributor.author

value: Hollick, Bernhard

value: Бернард, Холлик

dc.contributor.editor

value: Maltseva, Svetlana V.

value: Stanyukovich-Denisova, Ekaterina Yu.

value: Zakharova, Anna V.

value: Мальцева, С.В.

value: Станюкович-Денисова, Е.Ю.

value: Захарова, А.В.

dc.identifier.citation

value: Bernhard Hollick. The Poet as a Saint: The Caxton Master’s Portrait of Ovid and Its Literary Background. Actual Problems of Theory and History of Art: Collection of articles. Vol. 5. Eds: Svetlana V. Maltseva, Ekaterina Yu. Stanyukovich-Denisova, Anna V. Zakharova. St. Petersburg, NP-Print Publ., 2015, pp. 433–440. ISSN 2312-2129. http://dx.doi.org/10.18688/aa155-4-47

value: Бернард Холлик. Поэт в образе святого: портрет Овидия работы «кекстонского мастера» — литературная подоплека // Актуальные проблемы теории и истории искусства: сб. науч. статей. Вып. 5. / Под ред. С.В. Мальцевой, Е.Ю. Станюкович-Денисовой, А.В. Захаровой. – СПб.: НП-Принт, 2015. С. 433–440. ISSN 2312-2129. http://dx.doi.org/10.18688/aa155-4-47

dc.description.abstract

value: The frontispiece of William Caxton’s Middle English translation of the Ovide moralisé en prose in Cambridge, Magdalen College, Old Library, Ms. F.4.34, fol. 16r, shows Ovid as a Christian saint, praying to and receiving inspiration from an image of Christ. There is no similar picture in any other manuscript. However, the artist, who is usually referred to as the Caxton Master, could draw on a broad literary background: the text illustrated by him belongs to a group of sources from France, which offer Christian interpretations (the so-called moralisations) of the Metamorphoses. At the same time, the Caxton Master is rooted in a home-grown English classicism, which from 1300 onwards established Ovid as a major authority, as is evident by commentaries, sermons, and — most surprisingly — scholastics writings. This paper aims to shed light on this interaction of literature and art.

value: На фронтисписе перевода Ovide moralisé en prose на среднеанглийский язык, изданного Уильямом Кекстоном (Cambridge, Magdalen College, Old Library, Ms. F.4.34, fol. 16r), изображен Овидий, представленный в облике христианского святого, обращающегося в молитве и вдохновляемого образом Христа. Такое изображение не встречается более ни в одном манускрипте. Тем не менее художник, известный как «кекстонский мастер», мог ориентироваться на многочисленные книжные образцы: проиллюстрированный им текст восходит к французским источникам, в которых содержатся христианские интерпретации (так называемые морализации) «Метаморфоз». В то же время творчество «кекстонского мастера» вырастает из местного, исконно английского классицизма, в котором Овидию начиная с 1300-х гг., как явствует из комментариев, текстов проповедей и — самое удивительное — трудов схоластов, отводилось весьма авторитетное место. Цель статьи состоит в том, чтобы осветить взаимодействие литературы и изобразительного искусства.

dc.language.iso

value: en

dc.publisher

value: NP-Print

value: НП-Принт

dc.subject

value: Bersuire

value: Bradwardine

value: Caxton

value: frontispiece

value: Ovid

value: Ovide moralisé

value: portrait

value: Walsingham

value: Пьер Берсюир

value: Томас Брадвардин

value: Уильям Кекстон

value: фронтиспис

value: Овидий

value: портрет

value: Фрэнсис Уолсингем

dc.title.alternative

description: Article

description: Cover


title: The Idea of Rome beyond Rome

dc.contributor.author

value: Uscatescu, Alexandra

value: Александра, Ускатеску

dc.contributor.editor

value: Maltseva, Svetlana V.

value: Stanyukovich-Denisova, Ekaterina Yu.

value: Zakharova, Anna V.

value: Мальцева, С.В.

value: Станюкович-Денисова, Е.Ю.

value: Захарова, А.В.

dc.identifier.citation

value: Alexandra Uscatescu. The Idea of Rome beyond Rome. Actual Problems of Theory and History of Art: Collection of articles. Vol. 5. Eds: Svetlana V. Maltseva, Ekaterina Yu. Stanyukovich-Denisova, Anna V. Zakharova. St. Petersburg, NP-Print Publ., 2015, pp. 369–385. ISSN 2312-2129. http://dx.doi.org/10.18688/aa155-4-39

value: Александра Ускатеску. Идея Рима после Рима // Актуальные проблемы теории и истории искусства: сб. науч. статей. Вып. 5. / Под ред. С.В. Мальцевой, Е.Ю. Станюкович-Денисовой, А.В. Захаровой. – СПб.: НП-Принт, 2015. С. 369–385. ISSN 2312-2129. http://dx.doi.org/10.18688/aa155-4-39

dc.description.abstract

value: The weight of the Classical culture during the Middle Ages is undeniable and in this context, Roman art seems to play two opposing roles: the basis for the development of mediaeval art and a privileged source from which models are extracted. The issue is rather complex, so this argument will be supported by a single iconographic element embedded in the discourse of the idea of Rome: the she-wolf and the twins. This icon summarizing the idea of Rome survived its destruction and was adopted by other peoples alien to the Roman Empire. This paper is focused on the reception and re-use of that icon by Anglo-Saxon, Frank or Lombard peoples, between 5th and 9th centuries.

value: Значение античной культуры в эпоху Средневековья не подлежит сомнению. В этом контексте римское искусство играло две противоположные роли: фундаментальной основы развития средневекового искусства и первостепенного источника образцов для заимствования. Тема довольно сложная, и в подтверждение своей мысли автор обращается лишь к одному иконографическому примеру, задействованному в рассуждениях относительно идеи Рима: к образу волчицы и близнецов. Этот образ, обобщающий идею Рима, пережил его падение и был воспринят другими народами, не входившими в состав Римской империи. В статье рассматривается проблема восприятия и переработки этого образа англо-саксонскими, франкскими и ломбардскими народами в период между V и IX вв.

dc.subject

value: Anglo-Saxons

value: iconography

value: Late Antiquity

value: Lombard

value: Lupa Romana

value: Romulus and Remus

value: Sogdian

value: visual culture

value: англосаксы

value: иконография

value: Поздняя античность

value: Римская волчица

value: Ромул и Рем

value: изобразительная культура.

dc.title

value: The Idea of Rome beyond Rome

value: Идея Рима после Рима

dc.type

value: Article

description: Article

description: Cover


dc.contributor.author

value: Cerone, Roberta

value: Роберта, Чероне

dc.contributor.editor

value: Maltseva, Svetlana V.

value: Stanyukovich-Denisova, Ekaterina Yu.

value: Zakharova, Anna V.

value: Мальцева, С.В.

value: Станюкович-Денисова, Е.Ю.

value: Захарова, А.В.

dc.identifier.citation

value: Roberta Cerone. Cives romani in marmoris arte periti: the Classical World and the Renewal of the Cloister Model in 13th century Rome. Actual Problems of Theory and History of Art: Collection of articles. Vol. 5. Eds: Svetlana V. Maltseva, Ekaterina Yu. Stanyukovich-Denisova, Anna V. Zakharova. St. Petersburg, NP-Print Publ., 2015, pp. 412–417. ISSN 2312-2129. http://dx.doi.org/10.18688/aa155-4-44

value: Роберта Чероне. Cives romani in marmoris arte periti: античный мир и обновление модели клуатра в Риме XIII века // Актуальные проблемы теории и истории искусства: сб. науч. статей. Вып. 5. / Под ред. С.В. Мальцевой, Е.Ю. Станюкович-Денисовой, А.В. Захаровой. – СПб.: НП-Принт, 2015. С. 412–417. ISSN 2312-2129. http://dx.doi.org/10.18688/aa155-4-44

dc.description.abstract

value:
An introduction of the cloister in Rome starts in the 12th century (Tre Fontane, S. Lorenzo fuori le mura, S. Cecilia in Trastevere), but it’s only in the 13th century that we find a systematic usage of the cloister as the main element in planning of old and new monastic foundations.
	In parallel with its spreading the typical Roman cloister, as it was codified during the 12th century, undergoes a radical change, partly due to the involvement of the different artists of Roman marmorarii families: Cosmati and Vassalletto. These sculptors considered themselves discendants of Classical Rome and, in the name of that heritage, they reinterpreted forms and motifs of architectural sculpture from Roman period through the reuse and the reworking of marbles taken from ancient monuments. This change started in the monastery of S. Scolastica in Subiaco near Rome under the aegis of pope Innocent III and then involved the main complexes of the Urbe.

value: Появление крытых галерей в Риме относят к XII в. (Монастырь Трех источников, Сан-Лоренцо-фуори-ле-Мура, Санта-Чечилия-ин-Трастевере), но систематическое использование крытых галерей как основного конструктивного приема в старых и новых монастырских постройках относится к XIII в. По мере распространения типичный римский клуатр радикально изменился, отчасти в результате деятельности художников, представителей римских семей резчиков по мрамору — Козмати и Вассалетто. Эти скульпторы считали себя наследниками классического Рима и во славу этого наследия придавали формам и мотивам римской архитектурной пластики новую интерпретацию, вторично используя и перерабатывая мраморы, взятые с античных памятников. Первые изменения такого рода происходили в монастыре Св. Схоластики Нурсийской в Субиано близ Рима под эгидой папы Иннокентия III, а затем в главном комплексе в Урбе.

dc.language.iso

value: en

dc.publisher

value: NP-Print

value: НП-Принт

dc.subject

value: cloisters

value: medieval Rome

value: monastery of S. Scolastica at Subiaco

value: pope Innocent III

value: Magister Iacobus

value: Roman marble workers

value: крытые галереи

value: средневековый Рим

value: монастырь Св. Схоластики Нурсийской

value: папа Инокентий III

value: магистр Якобус

value: римские мастера по мрамору

dc.title.alternative

description: Article

description: Cover


dc.contributor.author

value: Ponchia, Chiara

value: Кьяра, Понкья

dc.contributor.editor

value: Мальцева, С.В.

value: Станюкович-Денисова, Е.Ю.

value: Захарова, А.В.

dc.identifier.citation

value: Chiara Ponchia. Suggestions from Antiquity. Discovering Classical Iconographies in the Trecento Divine Comedy Illustrations. Actual Problems of Theory and History of Art: Collection of articles. Vol. 5. Eds: Svetlana V. Maltseva, Ekaterina Yu. Stanyukovich-Denisova, Anna V. Zakharova. St. Petersburg, NP-Print Publ., 2015, pp. 426–432. ISSN 2312-2129. http://dx.doi.org/10.18688/aa155-4-46

value: Кьяра Понкья. Рекомендации из античности: открытие классической иконографии в иллюстрациях к «Божественной комедии» эпохи треченто // Актуальные проблемы теории и истории искусства: сб. науч. статей. Вып. 5. / Под ред. С.В. Мальцевой, Е.Ю. Станюкович-Денисовой, А.В. Захаровой. – СПб.: НП-Принт, 2015. С. 426–432. ISSN 2312-2129. http://dx.doi.org/10.18688/aa155-4-46

dc.description.abstract

value: After Dante’s death (1321), the Divine Comedy quickly became one the most appreciated works of Italian literature. Its spreading was impressively wide, since from the first half of the 14th century patrons asked for illuminated manuscripts of the poem, looking for a visual support to imagine Dante’s pilgrimage through the Hereafter. Therefore, illuminators had to face the difficult challenge of illustrating the text with no previous iconographic tradition. The easiest way to deal with this issue was turning to other sources, choosing among them the most suitable iconographies to be re-used in Dante’s masterpiece illustration. In this article we will see that, just as Dante’s literary sources were both mediaeval and classical, the illuminators’ quest for images wasn’t limited to contemporary sources, and in some cases we might find the echo of Сlassical models in the Divine Comedy illustrations.

value: После смерти Данте в 1321 г. «Божественная комедия» очень быстро стала одним из наиболее признанных произведений итальянской литературы и получила весьма широкое распространение. Начиная с первой половины XIV в. заказчики манускриптов требовали, чтобы текст сопровождался миниатюрами, изображающими путешествие Данте по загробному миру. В результате иллюстраторы столкнулись со сложной задачей оформления текста, не имевшего в прошлом иконографической традиции. Самым простым способом справиться с проблемой был поиск и использование наиболее подходящей иконографии из других источников. Автор статьи отмечает, что подобно тому, как Данте находил источник своей поэзии и в средневековой, и в античной традиции, так и иллюстраторы в поисках нужного образа пользовались не только современными им источниками. В некоторых случаях можно говорить об отголосках античных образцов для иллюстраций к «Божественной комедии».

dc.subject

value: history of illuminated manuscripts

value: Divine Comedy

value: Italian illumination

value: mediaeval art

value: iconography and iconology

value: Classical heritage

value: история иллюстрированных рукописей

value: «Божественная комедия»

value: итальянская миниатюра

value: средневековое искусство

value: иконография и иконология

value: наследие античности

dc.type

value: Article

description: Article

description: Cover


dc.contributor.author

value: Skvortcova, Ekaterina

value: Скворцова, Е.А.

dc.contributor.editor

value: Maltseva, Svetlana V.

value: Stanyukovich-Denisova, Ekaterina Yu.

value: Zakharova, Anna V.

value: Мальцева, С.В.

value: Станюкович-Денисова, Е.Ю.

value: Захарова, А.В.

dc.identifier.citation

value: Ekaterina Skvortcova. Illustrations to “Dialogues of the Dead”: a Problem of the Validation of the Title of the Russian Emperor in the 18th Century. Actual Problems of Theory and History of Art: Collection of articles. Vol. 5. Eds: Svetlana V. Maltseva, Ekaterina Yu. Stanyukovich-Denisova, Anna V. Zakharova. St. Petersburg, NP-Print Publ., 2015, pp. 503–512. ISSN 2312-2129. http://dx.doi.org/10.18688/aa155-6-55

value: Скворцова Е. А. Иллюстрации к «Разговорам в царстве мертвых»: проблема утверждения титула императора России в XVIII веке // Актуальные проблемы теории и истории искусства: сб. науч. статей. Вып. 5. / Под ред. С.В. Мальцевой, Е.Ю. Станюкович-Денисовой, А.В. Захаровой. – СПб.: НП-Принт, 2015. С. 503–512. ISSN 2312-2129. http://dx.doi.org/10.18688/aa155-6-55

dc.description.abstract

value: Being a form of politically-charged advocacy journalism, in the 18th century a genre of “Dialogues of the Dead” was to contribute to the discussion of a newly-gained title of a Russian ruler — a title of the Emperor. It is treated both in Russian works, which suggest growing ambitions of the Russian state, and in European ones, indicative of the response to them from abroad. A series of “Dialogues” by a German writer D. Fassman demonstrates gradual recognition of Russia’s new status in the international arena during the second quarter of the 18th century, as reflected in the validation of the title of Russian Emperor. Engraved illustrations on frontispieces embody the perception of Russia and Russian monarch and in some cases add new tints to the text. The evolution of the genre is evident in “Conversation of portraits and medallions”, written by Catherine II on the Chesme Palace (not earlier than the late 1770s) which featured a gallery of painted portraits of European monarchs — Catherine II’s contemporaries and bas-relief portraits of her predecessors on the Russian throne — Russian princes, tsars and Emperors. A modified subject-matter as well as the literary style makes it more compelling than traditional “Dialogues of the Dead”. Pieces of art are no longer accompanying material (illustrations), but a source of inspiration for creating a text. “Dialogues of the dead” chimed brilliantly with the way of artistic thinking typical for 18th century, with its specific figurative historicism, reflected in bringing together historical characters from different epochs.

value: В XVIII в. одной из тем распространенного жанра «Разговоров в царстве мертвых» становится утверждение имперского достоинства правителя России. Она нашла воплощение как в русских сочинениях, передающих амбиции возмужавшего государства, так и в европейских, отражающих реакцию на них извне. Серия «Разговоров…» немецкого писателя Д. Фассмана демонстрирует постепенное признание статуса России на международной арене на протяжении второй четверти XVIII в., выразившееся в признании императорского титула российского монарха. Гравированные иллюстративные фронтисписы наглядно фиксируют восприятие русского самодержца. Эволюцию жанра демонстрирует близкий «Разговорам в царстве мертвых» «Разговор портретов и медальонов», написанный Екатериной II по поводу Чесменского дворца (не ранее конца 1770-х гг.), в котором были представлены живописные портреты европейских монархов — ее современников и скульптурные — русских князей, царей и императоров. Найденные в этом литературном опусе стиль и сюжетно-эмоциональное обоснование сообщают повествованию живую убедительность. Произведения изобразительного искусства здесь не сопроводительный материал — иллюстрация, а напротив, источник для создания текста. «Разговоры в царстве мертвых» были жанром, органичным для художественного мышления XVIII в. со свойственным ему особым образным историзмом, имеющим выражение в сведении в одном произведении персонажей разных эпох.

dc.language.iso

value: ru

dc.publisher

value: NP-Print

value: НП-Принт

dc.subject

value: Dialogues of the Dead

value: a title of the Russian Emperor

value: German advocacy journalism of the second quarter of the 18th century

value: Rossica

value: Russia in perception of foreigners

value: dynastic portrait galleries

value: a word and an image

value: book illustration

value: «Разговоры в царстве мертвых»

value: императорский титул

value: немецкая публицистика второй четверти XVIII в.

value: россика

value: Россия глазами иностранцев

value: династические портретные галереи

value: слово и изображение

value: книжная графика

dc.title.alternative

description: Article

description: Cover